Removing CO2 at the Source

From the Air and from the Earth

Biogenic and direct capture technologies close the carbon loop

Direct Air Capture & Biogenic Removal

While point-source carbon capture offers a solution to prevent new CO2 emissions from entering the atmosphere, it does not address the existing high concentration of CO2 already present. To tackle this, a separate and increasingly popular technology known as Direct Air Capture (DAC) has emerged. DAC provides a corrective approach by actively removing CO2 from the atmosphere, making it especially valuable for offsetting historical emissions and addressing sectors that are particularly difficult to decarbonize, such as transportation.

One key advantage of DAC is its geographic flexibility, it is not tied to a specific emission source and can be deployed in locations with abundant renewable energy, which is crucial given the technology’s current limitation: high energy consumption. DAC typically requires around 6–9 GJ of energy per ton of CO2 captured [1], largely due to the low concentration of CO2 in ambient air compared to industrial flue gases.

DAC systems commonly rely on two main approaches: chemical absorption (Liquid DAC or L-DAC) and solid adsorption (Solid DAC or S-DAC). In L-DAC, CO2 is captured using aqueous basic solutions, such as potassium hydroxide, and then released through regeneration processes operating at high temperatures (300–900 °C) or electrolysis. In contrast, S-DAC uses solid adsorbents that work under ambient or low-pressure conditions and release CO2 when heated to moderate temperatures (80–120 °C). Emerging technologies like Electro Swing Adsorption use electrochemical cells where solid electrodes adsorb CO2 when negatively charged and release it when the charge is reversed. According to International Energy Agency [1] , as of now, 27 DAC facilities have been commissioned across the world. Most are small-scale demonstration plants, with only a few operating under commercial agreements for CO2 sale or storage. It is projected that DAC deployment could reach approximately 3 Mt captured CO2 by 2030.

How Photosynthesis Captures CO2

Nature has inherently capture CO2 to using it for photosynthesis. In plants, a leafy canopy creates an expansive surface area that, combined with wind flow and optimised sunlight absorption. From there, the solar photons are directly used to transform CO2 to hydrocarbons. Light up to 700nm in wavelength is used to transform water and carbon dioxide to glucose and oxygen:
6H2O + 6CO2   →  C6H12O6 + 6O2.

For this synthesis between 48 and 60 photons are necessary. The total energy necessary for the conversion requires approximately 50MJ/kg of glucose and has an efficiency of 30%. Crop, trees and bacteria filter the air and the waters to transform carbon dioxide into oxygen and glucose-like molecules. This glucose is then utilized for biomass growth, effectively serving as a temporary carbon storage medium. Over time, the stored carbon is released back into the atmosphere either through natural decomposition processes or through human activities such as bioenergy production. In the case of bioenergy, the resulting biogenic CO2 is reintroduced into the carbon cycle, allowing for potential recapture and reuse within a closed-loop system.  CO2 capture from biomass processing if combined with permanent storage are commonly known as bioenergy with carbon capture and storage (BECCS) scheme.

Ancient Method, Modern Potential

The natural carbon cycles by cultivating trees and crops can be leveraged for different purposes. One pathway is using wood as a renewable fuel source, which releases the energy originally stored in glucose through photosynthesis. When burned, wood can release approximately 15 MJ of heat per kilogram (based on the release of 0.3 × 50 MJ from the glucose content). Another, more sustainable alternative is converting wood into charcoal through pyrolysis, an ancient process involving thermal decomposition in a low-oxygen environment. In this process, about 6 MJ of energy is released per kilogram of wood, while approximately 0.3 kg of charcoal remains, retaining around 9 MJ of stored photosynthetic energy. This carbon-rich product can serve as a long-term carbon sink or as a renewable solid fuel, reducing reliance on fossil-based alternatives.

Industrial-Scale Carbon Sinks

Nowadays the pyrolysis can be done much cleaner and at oxygen-free condition even on industrial scale. One of such pyrolysis method is called torrefaction. Unlike traditional charcoal production, torrefaction can handle a much broader range of feedstocks, including agricultural residues such as straw and crop biomass, transforming them into a stable carbon-rich product known as biochar. Biochar can be used as biofuel, as material for chemical products such as catalyst support or it can be used for stored CO2 by  creating a carbon sink Although this natural method of CO2 capture does not produce CO2 feedstock as an output, it remains a highly effective strategy for reducing atmospheric CO2 levels. Storing one ton of carbon in biochar is theoretically equivalent to sequestering approximately 3.7 tons of CO2. Biochar production can be eligible for carbon credits, with the number of credits per ton of biochar, particularly from woody biomass, ranging from 2.57 to 3.26, and averaging around 2.83 credits per ton, depending on the feedstock and processing method used.
Turn CO2 into long-term value
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